New nanoparticle method developed at UA

 Keith Roper, an engineering researcher at the University of Arkansas, and research colleagues at the University of Utah have discovered a new method of making nanoparticles and nanofilms to be used in developing better electronic devices, biosensors and certain types of high-powered and highly specific microscopes used for scientific research.

Building faster, more efficient and more reliable electronic devices requires work at the molecular level with nanoparticles, according to a press release from the University of Arkansas.

Nanoparticles, which are too small for the human eye to see, can be the foundation for new processing hardware. A nanometer is a billionth of a meter. A human hair typically has a diameter of 70,000 nanometers.

The researchers’ nanoparticles, made of gold and deposited onto silicon substrates by a unique chemical process, are nontoxic and inexpensive to make and have superior dimensions, densities and distribution when compared to other nanoparticles and conventional methods of producing nanoparticles. The unique deposition technique has the further advantage of being able to rapidly coat fragile, three-dimensional and internal surfaces at the temperature and pressure of its surroundings without requiring conductive substrates or expensive, sophisticated equipment.

“Using successive thermal treatments, we characterized optical and structural features of an inexpensive, molecule-to-molecule, bottoms-up approach to create thermally stable, gold-nanoparticle ensembles on silica,” Keith Roper, associate professor of chemical engineering at the University of Arkansas, noted in the statement. “Images and analysis from scanning electron microscopy and atomic force microscopy revealed that particle densities are the highest reported to date. Our method also allows faster preparation than self-assembly or lithography and allows directed assembly of nanoparticle ensembles on 3D surfaces.”

Roper said microscopic images and spectroscopic data suggest that ultrathin films prepared by their new approach are smoother than conventional “sputtered” or evaporated gold films and may exhibit better optical features, such as reduced surface-roughness scattering. These features are desirable in devices such as photovoltaic cells in which narrow metal layers significantly affect local electromagnetic fields. Smoother thin films also could improve the limits of detection, sensitivity and photocurrent, respectively, in such applications.

The researchers’ recent studies in this area have been published in Langmuir and Journal of Physical Chemistry C, journals of the American Chemical Society. The researchers were awarded U.S. Patent No. 8,097,295 on Jan. 17 for the development.

Roper is holder of the Charles W. Oxford Professorship of Emerging Technologies. He is also assistant director of the graduate program in microelectronics/photonics.